Question
18 Figure 7 shows the displayed formulae equation for the reaction of nitrogen with hydrogen. Figure 7 [ mathrm(N) equiv mathrm(N)+mathrm(SH)-mathrm(H) longrightarrow 2 mathrm(H)-mathrm(N)-mathrm(H) ] H In the reaction the energy released forming new bonds is 93 mathrm(kJimol) greater than the energy needed to break existing bonds. Table 3 shows bond energies. Table 3 Bond & mathrm(N)=mathrm(N) & mathrm(H)-mathrm(H) & mathrm(N)-mathrm(H) Bond energy in mathrm(kJ) / mathrm(mol) & 945 & mathrm(X) & 391 Bond & mathrm(N)=mathrm(N) & mathrm(H)-mathrm(H) & mathrm(N)-mathrm(H) Bond energy in mathrm(kJ) / mathrm(mol) & 945 & mathrm(X) & 391 0 longdiv ( 5 ) cdot 3 Calculate the bond energy mathrm(X) for the mathrm(H)-mathrm(H) bond. [5 marks] Use Figure 7 and Table 3. omega arrow
Answer
4.3
(96 Votes)
Rosalind
Elite · Tutor for 8 years
Answer
The bond energy
for the
bond is
.
Explanation
## Step 1: Firstly, we need to understand the reaction given. The reaction is:
This means that one molecule of nitrogen (N) reacts with three molecules of hydrogen (H) to form two molecules of ammonia (NH3).## Step 2: Next, we need to calculate the total energy needed to break the bonds in the reactants. According to Table 3, the bond energy of N=N is 945 kJ/mol and the bond energy of N-H is 391 kJ/mol. Since there is one N=N bond and three N-H bonds in the reactants, the total energy needed to break the bonds in the reactants is:###
## Step 3: We are given that the energy released forming new bonds is 93 kJ/mol greater than the energy needed to break existing bonds. This means that the total energy released when the new bonds are formed is:###
## Step 4: Finally, we need to calculate the bond energy of the H-H bond. According to the reaction, there are six H-H bonds in the products (two in each NH3 molecule). Therefore, the bond energy of the H-H bond is:###