Question
The combustion of a fuel will be spontaneous at T=0 because it is an exothermic reaction, but will it stay that way when the temperature increases? Choose a hypothesis: a) Delta G will stay negative b) Delta G will change sign when T gets high enough
Answer
4.2
(192 Votes)
Georgia
Veteran · Tutor for 12 years
Answer
### b)
will change sign when
gets high enough
Explanation
## Step 1: Understand Gibbs Free Energy (
) Relation### Gibbs Free Energy (
) is given by the equation
, where
is the enthalpy change,
is the temperature, and
is the entropy change. For an exothermic reaction,
is negative.## Step 2: Conditions for Spontaneity### A reaction is spontaneous if
is negative. Initially, at
,
depends primarily on
, which is negative. As temperature increases,
becomes more significant. Depending on the sign of
, this can alter
.## Step 3: High Temperature Effect### If
is positive, increasing
will make
larger, potentially making
less negative or even positive. If
is negative, increasing
will make
more negative.