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Q1. In a time of flight mass spectrometer molecule X is ionised using electrospray ionisation. What is the equation for this ionisation? A X(I)+e^-arrow X^+(g)+2e^- square B X(g)+e^-arrow X^+(g)+2e^- square C X(I)+H^+arrow XH^+(g) square D X(g)+H^+arrow XH^+(g) square

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Q1.
In a time of flight mass spectrometer molecule X is ionised using electrospray
ionisation.
What is the equation for this ionisation?
A X(I)+e^-arrow X^+(g)+2e^-
square 
B X(g)+e^-arrow X^+(g)+2e^-
square 
C X(I)+H^+arrow XH^+(g)
square 
D X(g)+H^+arrow XH^+(g)
square

Q1. In a time of flight mass spectrometer molecule X is ionised using electrospray ionisation. What is the equation for this ionisation? A X(I)+e^-arrow X^+(g)+2e^- square B X(g)+e^-arrow X^+(g)+2e^- square C X(I)+H^+arrow XH^+(g) square D X(g)+H^+arrow XH^+(g) square

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HeleddProfessional · Tutor for 6 years

Answer

D<br />The option that correctly shows the ionization process with electrospray ionization in a time of flight mass spectrometer is D \( X(g)+H^+ \rightarrow XH^{+}(g) \).

Explain

## Step 1: Define the electrospray ionisation process<br />Electrospray ionisation is a technique used in mass spectrometry to ionise a molecule. The reaction involves adding a proton (H+) to the analyte.<br /><br />## Step 2: Evaluate option C<br />Option C \( X(I)+H^+ \rightarrow XH^{+}(g) \) shows an atom X in the state of iodine (I) getting ionized by adding a proton (H+), and then forming an ionised hydrogen molecule in gaseous state. However, it is a mistake because X should be in gaseous state (as the process we are analyzing takes place within a mass spectrometer).<br /><br />## Step 3: Evaluate option D.<br />Option D \( X(g)+H^+ \rightarrow XH^{+}(g) \) shows a gaseous X atom getting ionised by adding a hydrogen proton (H+), and then forming an ionised hydrogen molecule in gaseous state. This is the correct representation of an electrospray ionization process.
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