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Ex. 2 Complete the following equations,write main products : CH_(2)=CHC(CH_(3))_(3)+HBrarrow CH_(3)CH=CH_(2)+HBrxrightarrow (ROOR) (3) +KMnO_(4)xrightarrow (acidic) (4) CH_(3)leftharpoons CH+HBrarrow (5) CH_(3)Cequiv CCH_(3)+KMnO_(4)xrightarrow (acidic)

Question

Ex. 2 Complete the following equations,write main products :
CH_(2)=CHC(CH_(3))_(3)+HBrarrow 
CH_(3)CH=CH_(2)+HBrxrightarrow (ROOR)
(3) +KMnO_(4)xrightarrow (acidic)
(4) CH_(3)leftharpoons CH+HBrarrow 
(5) CH_(3)Cequiv CCH_(3)+KMnO_(4)xrightarrow (acidic)

Ex. 2 Complete the following equations,write main products : CH_(2)=CHC(CH_(3))_(3)+HBrarrow CH_(3)CH=CH_(2)+HBrxrightarrow (ROOR) (3) +KMnO_(4)xrightarrow (acidic) (4) CH_(3)leftharpoons CH+HBrarrow (5) CH_(3)Cequiv CCH_(3)+KMnO_(4)xrightarrow (acidic)

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UnaElite · Tutor for 8 years

Answer

1. $CH_{2}=CHC(CH_{3})_{3}+HBr\rightarrow CH_{3}CHBrC(CH_{3})_{3}$<br />2. $CH_{3}CH=CH_{2}+HBr\xrightarrow {ROOR}\gt CH_{3}CH_{2}CH_{2}Br$<br />3. $I^{-} + KMnO_{4}\xrightarrow {acidic} I_{2}$<br />4. $CH_{3}CH=CH_{2}+HBr\rightarrow CH_{3}CHBrCH_{3}$<br />5. $CH_{3}C\equiv CCH_{3}+KMnO_{4}\xrightarrow {acidic} 2CH_{3}COOH$

Explain

1. The addition of HBr to an alkene follows Markovnikov's rule, where the hydrogen adds to the carbon with more hydrogen atoms.<br />2. In the presence of peroxides (ROOR), the addition of HBr to an alkene follows anti-Markovnikov's rule.<br />3. Potassium permanganate (KMnO₄) in acidic conditions oxidizes iodide (I⁻) to iodine (I₂).<br />4. The addition of HBr to an alkene follows Markovnikov's rule.<br />5. Potassium permanganate (KMnO₄) in acidic conditions oxidizes alkynes to carboxylic acids.
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