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NO_(2)(g)+NO_(3)(g)arrow N_(2)O_(5)(g) The reaction represented I above occurs in a single elementary step. The activation energy for the step is 18kJ/mol , and the overall energy change is -136kJ/mol What is the activation energy for the reverse step? Choose 1 answer: A 18kJ/mol B 118kJ/mol C 136kJ/mol D 154kJ/mol

Question

NO_(2)(g)+NO_(3)(g)arrow N_(2)O_(5)(g)
The reaction represented I above
occurs in a single elementary step.
The activation energy for the step is
18kJ/mol , and the overall energy
change is -136kJ/mol
What is the activation energy for the
reverse step?
Choose 1 answer:
A 18kJ/mol
B 118kJ/mol
C 136kJ/mol
D 154kJ/mol

NO_(2)(g)+NO_(3)(g)arrow N_(2)O_(5)(g) The reaction represented I above occurs in a single elementary step. The activation energy for the step is 18kJ/mol , and the overall energy change is -136kJ/mol What is the activation energy for the reverse step? Choose 1 answer: A 18kJ/mol B 118kJ/mol C 136kJ/mol D 154kJ/mol

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AshtonMaster · Tutor for 5 years

Answer

The activation energy for the reverse step is 154 kJ/mol.

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## Step 1<br />This problem involves the concept of activation energy in relation to the rearrangement of atoms during a chemical reaction. The activation energy for the reverse reaction is the sum of the activation energy of the forward reaction and the energy change of the reaction.<br />### **Activation Energy(reverse) = Activation Energy(forward) + Energy Change**<br />## Step 2<br />The given problem provides the following data: the activation energy of the forward reaction step is 18 kJ/mol, and the overall energy change of the reaction is -136 kJ/mol.<br />## Step 3<br />Substitute these values into the formula:<br />### **Activation Energy(reverse) = 18 kJ/mol + (-136 kJ/mol)**<br />## Step 4<br />Despite the energy change being negative (as the reaction is exothermic), when calculating the activation energy for the reverse step, the endothermic energy requirement asks for the sum of the forward activation energy and the absolute magnitude of the energy change. This is due to the fact that "a negative times a negative equals a positive".<br />## Step 5<br />Therefore, the activation energy for the reverse step is:<br />### **Activation Energy(reverse) = 18 kJ/mol + 136 kJ/mol**
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