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Type the correct answer in the box. Express the answer to two significant figures Given: [ mathrm(N)_(2)+3 mathrm(H)_(2) arrow 2 mathrm(NH)_(3) ] Bond & }(c) Bond Energy (mathrm(kJ) / mathrm(mol)) mathrm(N)=mathrm(N) & 942 mathrm(H)-mathrm(H) & 432 mathrm(N)-mathrm(H) & 386 Use the bond energies to calculate the change in enthalpy for the reaction. The enthalpy change for the reaction is kilojoules.

Question

Type the correct answer in the box. Express the answer to two significant figures
Given:
[
mathrm(N)_(2)+3 mathrm(H)_(2) arrow 2 mathrm(NH)_(3)
]

 Bond & }(c)
Bond Energy 
 (mathrm(kJ) / mathrm(mol)) 
 
 mathrm(N)=mathrm(N) & 942 
 mathrm(H)-mathrm(H) & 432 
 mathrm(N)-mathrm(H) & 386 


Use the bond energies to calculate the change in enthalpy for the reaction.
The enthalpy change for the reaction is kilojoules.

Type the correct answer in the box. Express the answer to two significant figures Given: [ mathrm(N)_(2)+3 mathrm(H)_(2) arrow 2 mathrm(NH)_(3) ] Bond & }(c) Bond Energy (mathrm(kJ) / mathrm(mol)) mathrm(N)=mathrm(N) & 942 mathrm(H)-mathrm(H) & 432 mathrm(N)-mathrm(H) & 386 Use the bond energies to calculate the change in enthalpy for the reaction. The enthalpy change for the reaction is kilojoules.

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EdwinMaster · Tutor for 5 years

Answer

To calculate the change in enthalpy (\(\Delta H\)) for the given reaction, we will follow these steps:1. Calculate the total energy required to break the bonds in the reactants.2. Calculate the total energy released when the bonds in the products are formed.3. Use the relationship \(\Delta H = \text{energy required to break bonds} - \text{energy released when new bonds form}\).Given reaction:\[\mathrm{N}_{2} + 3 \mathrm{H}_{2} \rightarrow 2 \mathrm{NH}_{3}\]From the table, we have the following bond energies:- \(\mathrm{N}=\mathrm{N}\): 942 kJ/mol- \(\mathrm{H}-\mathrm{H}\): 432 kJ/mol- \(\mathrm{N}-\mathrm{H}\): 386 kJ/molNow, let's calculate the energy required to break the bonds in the reactants:- For \(\mathrm{N}_{2}\), we have one \(\mathrm{N}=\mathrm{N}\) bond, so the energy required is \(1 \times 942\) kJ/mol.- For \(3 \mathrm{H}_{2}\), we have three \(\mathrm{H}-\mathrm{H}\) bonds, so the energy required is \(3 \times 432\) kJ/mol.Total energy required to break the bonds in the reactants:\[1 \times 942 + 3 \times 432 = 942 + 1296 = 2238 \text{ kJ/mol}\]Next, let's calculate the energy released when the bonds in the products are formed:- For \(2 \mathrm{NH}_{3}\), we have six \(\mathrm{N}-\mathrm{H}\) bonds (each \(\mathrm{NH}_{3}\) has three \(\mathrm{N}-\mathrm{H}\) bonds), so the energy released is \(6 \times 386\) kJ/mol.Total energy released when new bonds form:\[6 \times 386 = 2316 \text{ kJ/mol}\]Now, we apply the relationship for \(\Delta H\):\[\Delta H = \text{energy required to break bonds} - \text{energy released when new bonds form}\]\[\Delta H = 2238 - 2316\]\[\Delta H = -78 \text{ kJ/mol}\]The negative sign indicates that the reaction is exothermic, meaning it releases heat.Therefore, the enthalpy change for the reaction is **-78 kilojoules** when expressed to two significant figures.
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